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Technical
Information about Stainless Steel - Mill Forms
Standard
industry designations for stainless steel finishes are classified
by mill form, there being separate finishes (or conditions) for
plate, sheet and strip, bar, rod, wire and tubing. Standard finishes
applicable to each mill form are described below.
It
is worth noting that there is also a wide range of non standard
product finishes suitable for a variety of applications. Stainless
steels may be supplied with coloured finishes, textured finishes
or combinations of both, they may be electropolished for smoothness
or mechanically polished to a fine mirror finish. Finishes can also
be applied by fabricators or manufacturers (such as glass bead blasting).
Plate,
Sheet, Strip, Coil
Flat
products (plate, sheet, strip, coil) form the largest product sector
of the stainless industry.
For
most practical purposes it is not possible to measure the surface
appearance exactly. Samples which the human eye sees as different
can be measured as the same, and vice versa.
The
easiest thing to measure about the surface appearance is the surface
roughness. This is defined as the average deviation of the height
of the surface from the centre line of the surface (Ra), and is
usually measured with an instrument which drags a diamond stylus
across the surface. The movement of the stylus is converted into
an electrical signal, from which the Ra value is calculated electronically.
The calculation is made using a characteristic cut-off wavelength,
usually 0.8mm. The choice of cut-off wavelength is important as
it affects the Ra measured on a surface.
Manufacture
of Stainless Steel Flat Products
Today
almost all stainless steel is melted in an Electric Arc Furnace
(EAF) or Basic Oxygen Furnace (BOF), the chemistry is refined in
the ARgon Oxygen Decarburising process (AOD), and slabs made by
Continuous Casting. These slabs may be partially or fully surface
ground before being charged to a reheating furnace, then hot rolled
to plate or coil.
After
hot rolling plates are annealed by heating at high temperature (>1000C
to give a more consistent internal structure than can be achieved
by hot rolling. The resulting surface is designated "O"
or "HRA" - hot rolled and softened but not descaled. Infrequently,
plate in this condition may be used for economy where it would scale
in high temperature service anyway, but there is a chromium depleted
layer under the oxide and the steel surface is less corrosion resistant
than after pickling. The surface appears black and will undergo
superficial corrosion in wet conditions, although the corrosion
rate will generally be much slower than for carbon steel.
More
typically, plates are pickled to remove the high temperature oxide
and associated chromium depleted layer. This may include shot blasting
before pickling to crack the heavy black surface oxide to speed
the removal of the oxide and steel surface layer by the pickling
acid (mixture of nitric and hydrofluoric acids). This finish is
known as "S & D" (for softened and descaled), or "No
1", or "HRAP". Hot rolled coils are also treated
to produce this "S & D" finish before being cold rolled
and small amounts of 5 and 6 mm thick material are used in this
condition, where smoothness of finish is not iportant. Surface roughnesses
are generally in the range 2 - 6 micrometers. Grades respond differently
to the pickling acid, which may make them look different..
Plates
are commonly conditioned by the producer for the removal of surface
imperfections on either or both surfaces by hand grinding after
pickling provided the ground area is well merged.
Cold
rolling smoothes the steel surface with each succeeding pass through
the rolling mill.
The
bulk of stainless produced is cold rolled to reduce the thickness
by more than 50% and then reannealed in a furnace with an oxidising
atmosphere which oxidises the steel surface. This oxidation, and
subsequent pickling, roughens the cold rolled surface. The coils
are then given a final light skin pass on highly polished rolls
of large diameter, which reduces the roughness only slightly but
improves the lustre, as well as the flatness of the coil. The resulting
finish is "2B", the most common finish on stainless steels.
The
appearance of the finish is dominated bythe cold rolling reduction,
although many other factors affect the surface roughness. It is
not possibleto achieve matching surface finish at different steel
thickness. The roughness is largely determined by the total amount
of cold rolling and lies in the range 0.1 - 1.0 micrometers. Where
a rougher surface is needed for properties such as anti galling,
paint adhesion etc, the surface is termed "2D". This finish
may be achieved by supplying a surface in the "as-pickled"
condition, or by doing some of the cold rolling on roughened rolls.
The finish may be skin passed. "2D" surface roughness
is in the 0.5 - 3.0 micrometre range, although when roughened surface
rolls are used the wavelength of the surface undulations is too
long to be measured with the normal cut-off wavelength of 0.8mm.
The
most reflective mill finish is achieved by Bright Annealing in a
reducing dry nigtrogen/hydrogen atmosphere - "BA" finish.
The smooth surface developed by cold rolling is retained by the
annealing atmosphere which prevents oxidation of the surface. The
high reflectivity requred may require a smoother starting surface
prepared by surface grinding the coil before rolling. The surface
is too smooth to be measurable by common surface roughness instruments
and gloss measurement is the best available technique.
"No.
4" finish is produced by polishing the surface with abrasives.
A series of abrasive belts is used which give a decorative polished
finish widely used for restaurant and kitchen equipment, stoves,
refrigerators etc. No. 4 is generally finished with abrasives of
approximately 120 to 150 mesh, after initial grinding with coarser
abrasives. The coil may then be tension levelled or skin passed,
increasing the lustre of the surface.
The
grade and type of abrasive used, the number of belts used and their
condition, the head pressure and travel speed of the stock and whetere
the grinding process is lubricated or dry, all affect the appearance
of the finish. It is unlikely that No. 4 finish from different suppliers
will match, since there is no standardisation between suppliers.
In-market processors will omit the tension levelling or skin passing
step, giving a surface of lower lustre.
Different
grades also respond to a standard polishing streatment in different
ways, so grades will not match exactly. Of course, the variation
of finish with thickness seen with 2B does not apply to No. 4: different
thicknesses of the same grade should match. The roughness of No.
4 typically ranges from about 0.4 to 1.0 micrometers.
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